The dual nature of matter and radiation refers to the concept that particles of matter exhibit both particle-like and wave-like properties. This duality is a fundamental aspect of modern Physics. Electromagnetic radiation, such as light, behaves like a wave with characteristics such as wavelength, frequency, and interference patterns.
However, it can also be described as discrete packets of energy called photons, each carrying energy proportional to its frequency. In the early 20th century by pioneers like Max Planck, Albert Einstein, and Erwin SchrΓΆdinger, quantum mechanics describes particles and radiation with wave functions that evolve deterministically and probabilistically.
1.0Dual Nature Of Light
Light does not have a definite nature; rather, its nature depends on its experimental phenomenon. This is known as the dual nature of light.
2.0Types of Emission
Emission- It is a process of emission of electrons from a metal surface.
Thermionic Emission
Field Emission
Photoelectric Emission
Work Function(Ο) - It is the minimum energy an electron requires to escape from a metal surface. It is measured in electron volts(eV).
3.0Einsteinβs Quantum Theory of Light
Light behaves as Quanta. These energy quanta are called Photons, and they have definite Energy and Momentum and travel with the speed of light in a vacuum.
4.0Energy of Photon
Energy is radiated from the source in the form of small packets called photons.
According to Planck's Theory: Energy(E) β (Frequency)
It is a phenomenon of ejecting electrons by falling light of a suitable frequency or wavelength on a metal surface. Ejected electrons are called photoelectrons, and the current flowing due to these photoelectrons is called current.
10.0Saturation current
When all the photoelectrons emitted by the cathode reach the anode then current flowing in the circuit at that instant is known as saturation current; this is the maximum value of Photoelectric current.
11.0Stopping Potential
The minimum magnitude of the negative potential of the anode concerning the cathode for which the current is zero is called the stopping potential or cut-off voltage; this voltage is independent of intensity.
12.0Graph of Various Quantities
Graph of Various Quantities Observed from Lenardβs Experiment of Photoelectric Effect:
Photoelectric current versus Intensity of Light
Photoelectric Current versus stopping Potential (Frequency=Constant)
Photoelectric Current versus Stopping Potential (Frequency = variable)
Stopping Potential Versus Frequency
13.0Einstein Photoelectric Equation
The surface absorbs radiation in the form of photons. The Energy of each Photon depends on its frequency. At a time, only one Photon can interact with one electron.
The Energy of the photon used by the electron is,
hv = K.E of electron + Energy required to make electron free from the metal surface(0) + Energy lost in collision before emission (Q)
β΄ If Q = 0, means there is no heat loss, then K.E of electron is maximum.
eV0β=hvβhv0β (β΄v0β is the threshold frequency for that V0β=0)
K.E. and Stopping Potential (V0β) depend on frequency.
Kinetic Energy cannot be negative so that hu>hv0β
v>v0β (It means if frequency is less than β²v0β²β, electrons do not come out.
The Graph between K.E. and Frequency
14.0Quantum Efficiency
Quantum Efficiency (x)= total number of photons incident per second number of electrons emitted per second β=nph βneββ
If quantum efficiency is x % then neβ=100xβ[β΅nphβ=(5Γ1024Jβ1mβ1)PΞ»]
15.0Matter Waves and De Broglie Hypothesis
Waves associated with a moving particle are matter waves.
Matter waves are probabilistic because they can be expressed as probability density functions.
The Formula for de-Broglie wavelength
Ξ»=phβ=mvhβ=2mKβhβ
De-Broglie wavelength for a charged particle
Ξ»=2mqVβhβ
16.0Explanation of Bohr Quantisation Condition
According to De Broglie, electrons revolve around the nucleus in the form of stationary waves; electrons revolve in those circular orbits whose circumference is an integral multiple of the de-Broglie wavelength associated with the electrons.
2Οr=nΞ»
2Οr=nmvhβ
mvr=2Οnhββ¦β¦ This is Bohr quantisation Condition
rnβ=(0.529AΛ)Zn2β(β΄Z= Atomic number )
17.0Nucleus and Types of Nuclei
The Nucleus is a central core of every atom discovered by Rutherford in scattering experiment.
Order of nuclear size=10-15m and of atomic size=10-10 m
Atomic mass is expressed by atomic mass unit (u)
1u = 1.66 x 10-27 kg
18.0Types of Nuclei
Isotope- same Z
Isobar-same A
Isotone-same(A-Z)
Size of Nucleus : R=R0βA1/3 here, R0β=EmpiricalConstant=1.2fermi
Volume β Mass Number (A)
Density of Nucleus =4ΟR03β3mpββ=2.3Γ1017kg/m3
19.0Nuclear Forces and Its Properties
The most robust interaction holding nucleons together to form nuclei is strong enough to overcome the electric repulsion of protons and neutrons.
The most vital force in the universe.
Works only between the nucleons
Very short-range force
It depends on the distance
Charge independent
Spin dependent
Non-central force
Nature-(1) Attractive-distance greater than 0.8 fm (2) Repulsive-distance lesser than 0.8 fm.
20.0Mass Defect and Nuclear Binding Energy
Mass of a nucleus is always less than the sum of masses of its constituent nucleons;this difference is called the mass defect.
Ξm = [Zmp + (A - Z)Mn] - M
Binding energy (Eb) is the energy required to split it into its nucleons: Ebβ=Ξmβ c2
21.0Binding Energy per Nucleon Curve
The value of binding energy per nucleon decides the stability of the nucleus
The Greater the binding energy per nucleon ,the more stable the nucleus.
The maximum for Iron( Fe) is 8.8 Mev, the most stable nucleus.
For Uranium 7.7Mev it is unstable
Medium- sized nuclei are more stable than light or heavy nuclei.
22.0Difference between Nuclear Fission and Nuclear Fusion
Required Condition For Nuclear Fusion
High Temperature
High Pressure(Density)
In Nuclear Fission
Reproduction Factor (K)= Rate of Loss of neutrons Rate of Production of neutrons β
K = 1, a chain reaction will be steady or sustained.
K > 1, supercritical this will result in an explosion
K < 1, Sub critical chain reaction will retard and ultimately stops
23.0Radioactivity and Types of Process
Radioactivity is a process of spontaneous emission of radiation from the nucleus; only unstable nuclei exhibit this property.
Types of Process
24.0Difference Between alpha, beta and gamma Decay Process
25.0Rutherford's Atomic Model
Most of the particles went straight through gold foil and produced flashes on the screen.
Few particles deflected at large angles, and few turned back towards the source itself.
The entire positive charge and the whole mass of the atom are concentrated in a small centre called the nucleus.
Electrons cannot deflect the path of particle electrons, which are very light.
Distance of Closest Approach.
(r0β)=4ΟΟ΅0β(2ze)21β (where, EK = K.E. of Ξ±-particle)
Failures of Rutherford's Model
It could not explain the stability of the atom.
It could not explain the discrete nature of hydrogen spectra.
26.0Bohr Model of Hydrogen Atom
An electron in an atom moves around the nucleus in a circular orbit under the influence of Coulomb's force of attraction between electron and nucleus.
The total energy of the electron revolving in any of the stationary orbits remains constant.
Electromagnetic radiations are emitted if an electron jumps from a stationary orbit of higher energy E2 to another stationary orbit of lower energy E1.
E2ββE1β=hv
Drawbacks of Bohr's Model
This model does not explain the fine structures of spectral lines, Zeeman effect, Stark effect.
Valid for single electron system.
Model- based on circular orbit of electrons.
Not explain the intensity of spectral lines.
Not explain the doublets obtained in the spectra of some of the atoms.
This model is semi quantum model it includes two quantum numbers (E and L).
Formulas for Single Electron Species
(a) Radius of Orbits: rnβ=Οme2n2h2Ο΅0ββ
(b) Velocity of revolving electrons: V=2nhΟ΅0βe2β
(c) Frequency of electron in an orbit: v=4Ο΅02βh3n3me4β
(d) Electron Energy:Enβ=8n2h2Ο΅02ββme4β
(e) Frequency of Emitted Radiations
v=8Ο΅02βh3me4β[n12β1ββn22β1β]
Ξ»1β=8Ο΅02βh3cme4β[n12β1ββn22β1β]
(β΄R=8Ο΅02βh3cme4β, Rydberg Constant = 1.1 x 107m-1)
vΛ=Ξ»1β=R[n12β1ββn22β1β]
(f) Electron energy level in Hydrogen atom: Enβ=βn213.6βeV
27.0Spectral Series of Hydrogen Atom
vΛ=Ξ»1β=R[n12β1ββn22β1β]
Lyman series - This series lies in the ultraviolet region.
(a) First Member: Ξ»1β=R[121ββ221β]=43Rβ=Ξ»=1216AΛ
(b) Second Member: Ξ»1β=R[121ββ321β]=98Rβ=Ξ»=1026AΛ
Balmer Series- This series lies in the visible region and near the ultraviolet region
(a) First Member: Ξ»1β=R[221ββ322β1β]=365Rβ=Ξ»=6563AΛ
(b) Second Member: Ξ»1β=R[221ββ421β]=163Rβ=Ξ»=4861AΛ
(c) Third Member: Ξ»1β=R[221βββ21β]=Ξ»=3646AΛ
Paschen Series-This series lies in the infra- red region.
Ξ»1β=R[321ββn22β1β], for the first member the wavelength is 18750 Γ
Brackett Series- This series lies in Infra-red region: Ξ»1β=R[421ββn22β1β]
Pfund Series- This series lies in Infra-red region: Ξ»1β=R[521ββn22β1β]
28.0Solved Problems on Modern Physics
Question 1. Power of a radiator is 100 watt and its wavelength( Ξ») is 400 nm. Calculate No. of photons emitted in 10 hrs.
Solution:
n=(5Γ1024Jβ1mβ1)PΓΞ»
n = 5 Γ 1024 Γ 100 Γ 4 Γ 10β7 = 2 Γ 1020
N = n Γ t = 2 Γ 1020 Γ 10 Γ 3600 = 7.2 Γ 1024
Question 2. A source S1 is producing 1015 photon/s of wavelength 5000 Γ . Another source S2 is producing 1.02 Γ 1015 photon/s of wavelength 5100 Γ . Calculate ratio of power of S2 to power of S1.
Question 3. A beam of electromagnetic wave of power 10 watt is incident normally on a surface, which absorbs 40% power and remaining power is reflected. Calculate force exerted on a surface.
Solution:
F=cPiβ+Prββ=3Γ10810+6β=5.33Γ10β8N
Question 4. Find the ratio of de-Broglie wavelengths for a proton and an alpha particle, if both have the same speed.
Question 5. The work function of a metal is 2.3 eV and the wavelength of the incident photon is 4.8 Γ 10β7m. Find maximum kinetic energy of photoelectrons.